Hydrophobic and dispersible Cu(I) desulfurization adsorbent prepared from Pistia stratiotes for efficient desulfurization.

Improving the adsorption capacity of adsorbents is a good way to boost their desulfurization efficiency. Optimizing the dispersion of metal nanoparticles and enhancing the stability of the metal valence state are essential to maximizing the adsorption capacity of the metal-loaded desulfurization adsorbent. Pistia stratiotes can absorb the Cu in water and evenly disperse it throughout the plant, allowing the production of a highly dispersed Cu(I) adsorbent (PSAC-Cu(I)). During the usage and storage of PSAC-Cu(I), Cu(I) oxidizes to Cu(II) when it comes in contact with oxygen and water, reducing its adsorptive capacity; hence, we modified PSAC-Cu(I) hydrophobically using polydimethylsiloxane (PDMS) to generate PSAC-Cu(I)-P(200). The outcome of the two-month exposure experiments showed that only 4.7% of the Cu(I) of PSAC-Cu(I)-P(200) was oxidized in the humid atmosphere, whereas PSAC-Cu(I) was almost fully oxidized. Moreover, the dibenzothiophene adsorption capacity of PSAC-Cu(I)-P(200) in a model oil with a water concentration of 250 ppmw is 68 mg g-1, which is 1.62 times that of PSAC-Cu(I). When 10 wt% toluene was added to the model oil, the adsorption desulfurization capacity of PSAC-Cu(I)-P(200) decreased to 86.8% of the original. This shows that PSAC-Cu(I)-P(200) has good stability and excellent adsorptive desulfurization performance.

Evaluation of adsorptive desulfurization performance and economic applicability comparison of activated carbons prepared from various carbon sources.

Adsorptive desulfurization (ADS) using activated carbon (AC) as adsorbent presents competitive potential in separating thiophenic sulfur from liquid fuels with high selectivity under mild operation conditions. It is also a highly economic remedy in ultra-low sulfur content situations. Most importantly, a suitable feedstock for macroscopic quantity preparation of AC adsorbents with good adsorptive desulfurization performance and low-cost is required to satisfy the requirements of this field. In this work, four representative substances (i.e., coal, coconut shell, polyurethane plastic waste, and petroleum coke) were selected as the carbon source for the preparation of various AC adsorbents. The physicochemical properties of the prepared AC adsorbents were characterized using BET, SEM, XRD, XPS, elemental analysis and Boehm's method. The corresponding adsorptive desulfurization performance was investigated. The corresponding desulfurization capacity obtained was in the order: CS-ACA > PUPW-ACA > PC-ACA > AT-ACA. Under the optimal conditions of 30 °C and 30 min contact time, the desulfurization rate of 0.5 g PUPW-ACA can reach about 98%. The HHV of non-condensable gas generated during the experiment was calculated, and the HHV of the pyrolysis oil was measured. The results showed that the by-products produced by PC had the highest HHV. The economics of the desulfurization of the four kinds of activated carbon were analyzed and evaluated. From a comprehensive analysis, PUPW-ACA has the highest economic production value and has the potential for industrial production. This plays a dual role in environmental protection.